By John F Kennedy
Carbohydrate Chemistry presents overview insurance of all courses suitable to the chemistry of monosaccharides and oligosaccharides in a given yr. the quantity of analysis during this box showing within the natural chemical literature is expanding as a result of the greater value of the topic, specially in parts of medicinal chemistry and biology. In no a part of the sector is that this extra obvious than within the synthesis of oligosaccharides required by means of scientists operating in glycobiology. Clycomedicinal chemistry and its reliance on carbohydrate synthesis is now rather well validated, for instance, by way of the guidance of particular carbohydrate- established antigens, in particular cancer-specific oligosaccharides and glycoconjugates. assurance of themes corresponding to nucleosides, amino-sugars, alditols and cyclitols additionally covers a lot learn of relevance to organic and medicinal chemistry. each one quantity of the sequence brings jointly references to all released paintings in given parts of the topic and serves as a complete database for the energetic examine chemist expert Periodical stories supply systematic and designated evaluate assurance in significant components of chemical study. Compiled via groups of top gurus within the suitable topic parts, the sequence creates a special carrier for the lively study chemist, with commonplace, in-depth money owed of development particularly fields of chemistry. topic insurance inside diversified volumes of a given identify is identical and e-book is on an annual or biennial foundation.
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Additional info for Carbohydrate Chemistry Volume 15, Part Ii
1981, 209, 316. BiochemT 1981, 110, 397. , 1981, 113,130. Biochem. (Tokyo), 1981, 90, 407. , 1981, 223, 321. Wagstaffe, Analyst, 1980, 581. , 1981, 118, 162. Acta, 1981, 131,293. , 1981, 114,131. , 1981, 115,219. , 1981, 115, 170. , 1981, 115,308. , 1981, 214, 156. Horowitz, in 'Carbohydrates: Chemistry and Biochemistry', 2nd Edition, ed. 1445. , 1981, 118, 301. , 1981, 92, 131. , 1981, 98, 237. Acta, 1981, 128,195. , 1981, 110, 393. Acta, 1981, 111, 27. , 1981, 117,187. , 1980, 44, 2943. , 1981, 27, 1287.
1 48 Bacteroides thetaiotaomicron, a polgsaccharide degrading bacterium from the human colon,can use larch L-arabino-;-galactan as its carbon source with yields similar to those obtained on p-glucose. 149 The crystal structure of a regenerated form of (1+3)-a-D-glucan has been determined by X-ray diffraction analysis and stereochemical model refinement as an orthorhombic unit cell. 50 The chain conformation is almost completely extended and is very close to a 2/1 helix even though the dimer residue is the crystallographic repeat unit.
95 A well recorded 13C spectrum was obtained which could be assigned by comparison with the spectra of simpler sugars. The 13Cd and 13C results were not consistent with the formation of chelate-alcoholate complexes with the C-2 and C-3 hydroxy groups. Hydrogen bonding is probably the dominant interaction. It is further suggested that the metal ion serves the dual purpose of holding two amino groups in a favourable orientation to hydrogen bond with a pair of equatorial hydroxy groups on the cellulose.
Carbohydrate Chemistry Volume 15, Part Ii by John F Kennedy