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ISBN-10: 926405667X

ISBN-13: 9789264056671

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211 Table VIII-9: Molar Gibbs energies of formation at 25°C used in modelling the Th-fluoride system. 4).............................. 220 Table VIII-11: Summary of selected Δ f Gmο values for the aqueous Th-F species...... 221 Table VIII-12: Summary of selected equilibrium constants for reactions involving aqueous Th-F species.......................................................... 221 Table VIII-13: Solubility products of ThF4(cr, hyd) at 25°C according to the reaction: ThF4(cr, hyd) + 4H+ U Th4+ + 4HF(aq).

02 M HNO3; organic phase: TBP/n-dodecane). 0 (nitrate complexation model)....................... 5 M CaCl2 solutions; the calculated curves are based on the proposed SIT model parameters. 13), at 25°C and 1 bar. 2................................................................ 756 List of Tables Table II-1: Abbreviations for experimental methods. 9 Table II-2: Symbols and terminology. 11 Table II-3: Abbreviations used as subscripts of Δ to denote the type of chemical process. 15 Table II-4: Unit conversion factors.

609 Table A-65: Solubility constants log10 *K sο,0 at zero ionic strength re-evaluated from solubility studies of [1991FEL/RAI], [1997RAI/FEL] with fresh and aged ThO2(am, hyd).......................... 612 Table A-66: Equilibrium constants, − log10 *β n, m (Th m (OH) n4 m − n ) ± 3σ in 3 M NaClO4 and the standard deviation in the error-carrying variable E (in mV) from the least squares analysis of experimental data for the Th(IV)-hydroxide system. 613 Table A-67: Equilibrium constants for Th(IV) hydroxide and acetylacetonate complexes at 25ºC in 1 M NaClO4......................................................

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Chemical Thermodynamics Chemical Thermodynamics of Thorium by perrone


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