By Stefan Kubik (auth.), Markus Albrecht, Ekkehardt Hahn (eds.)

ISBN-10: 3642280595

ISBN-13: 9783642280597

Molecular Cages and drugs with Functionalized internal Surfaces, via Stefan Kubik. Drug supply via Water-Soluble Organ steel Cages, by means of Bruno Therrien. Reversibly multiplied Encapsulation Complexes, by way of Dariush Ajami und Julius Rebek. box Molecules in accordance with Imine kind Ligands, by means of A. Carina Schulze und Iris M. Oppel. Molecular drugs Derived from Resorcin[4]arenes by way of Metal-Coordination, by way of Tobias Schröder, Satya Narayan Sahu und Jochen Mattay. Coronates, round boxes, Bowl-Shaped Surfaces, Porous 1D-, 2D-, 3D-Metallo-Coordination Polymers, and Metallodendrimers, by means of Rolf W. Saalfrank und Andreas Scheurer.

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Inorganic Metalla-Assemblies . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Organometallic Metalla-Assemblies . . . . . . . . . . . . . . . . . . . . . . . . . . . . Organometallic Metalla-Assemblies Composed of Half-Sandwich Complexes . . . . . . Organometallic Assemblies Composed of Half-Sandwich Complexes for Biological Applications . . .

References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 37 39 42 44 48 52 52 B. Therrien (*) Institut de chimie, Universite´ de Neuchaˆtel, Av. ch 36 B. Therrien Abbreviations bipy bpe bpp bpy Cp Cp* DAniF dcbq dhbq doaq donq dotq en phen tpp tppp tpt 4,40 -Bipyridine 1,2-Bis(4-pyridyl)ethylene 5,15-Bis(4-pyridyl)-10,20-diphenylporphyrin 2,20 -Bipyrimidine Cyclopentadienyl Pentamethylcyclopentadienyl N,N0 -Di(p-anisyl)formamidinate 2,5-Dichloro-1,4-benzoquinone-3,6-diolato 1,4-Benzoquinone-2,5-diolato 1,4-Anthraquinone-9,10-diolato 1,4-Naphthoquinone-5,8-diolato Tetracene-5,12-dione-6,11-diolato Ethylenediamine 4,7-Phenanthroline 5,10,15,20-Tetra(4-pyridyl)porphyrin 5,10,15-Tris(4-pyridyl)-20-phenylporphyrin 1,3,5-Tris(4-pyridyl)triazine 1 Introduction The design of molecular hosts to encapsulate guest molecules in a confined environment is receiving considerable attention due to the analogy of these systems with the mode of action of enzymes.

3 Organometallic Metalla-Assemblies Built on the experience gained from the synthesis of inorganic metalla-assemblies, both, two- and three-dimensional architectures have been obtained with organometallic building blocks. The fac-Re(CO)3 corner unit was possibly the first 40 B. Therrien Fig. 6 Organometallic assemblies built with fac-Re(CO)3 units, {Re(CO)3}4(bipy)2(m-O)4 (a) [20] and {Re(CO)3}6(bpy)3(tpt)2 (b) [21] organometallic building block used for the rational design of metalla-cycles and three-dimensional metalla-assemblies [19].

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Chemistry of nanocontainers by Stefan Kubik (auth.), Markus Albrecht, Ekkehardt Hahn (eds.)


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