By K. Kuchitsu, E. Hirota, D. A. Ramsay, J. Vogt, N. Vogt (auth.), K. Kuchitsu, M. Tanimoto, N. Vogt (eds.)
Volume II/28 is a supplemented and revised version of the previous volumes II/7, II/15, II/21, II/23 and II/25, containing modern details at the geometric parameters (internuclear distances, bond angles, dihedral angles of inner rotation etc.) of loose inorganic and natural polyatomic molecules. All experimental tools for the selection of quantitative structural info of loose molecules were thought of: microwave, infrared, Raman, digital and photoelectron spectroscopy in addition to electron diffraction. the knowledge got via those tools were seriously evaluated and compiled. they're offered individually for every molecule, including a computer-drawn schematic determine of the constitution and the unique literature.
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Average angle between the a inertial axis and the HCl molecular axis. : Chem. Phys. Lett. 291 (1998) 190.
Lett. 257 (1996) 321. 052(3) D3h assumed AlCl3 The monomeric (71(3) mol%) and dimeric (29(3) mol%) forms were found to be present in the in vapor. The structural parameters of Al2Cl6 molecule were constrained to the values obtained the study at 150 °C, the difference between rα(Al–Cl) in the monomer and rα(Al–Cl(t)) in the dimer was assumed at the values from HF/6-31G(d) calculations. The nozzle temperature was 400 °C. a ) Twice the estimated standard error. : J. Phys. Chem. A 103 (1999) 1644. Replaces II/25A(2, 4) Landolt-Börnstein New Series II/28A Structure Data of Free Polyatomic Molecules 9 MW AlHS Aluminum hydrogen sulfide AlSH has a bent structure with a bond angle close to 90°.
1(31) θα No monomeric species of AlCl3 molecule were detected in the vapor. The effect of the largeamplitude ring puckering mode on the interatomic distances was handled by a dynamic model composed of a set of pseudoconformers. The differences between corresponding structure parameters in the pseudoconformers were constrained to the values from HF/6-31G(d) calculations. The nozzle temperature was 150 °C. a ) Twice the estimated standard errors including a systematic error. : J. Phys. Chem. A 103 (1999) 1644.
Inorganic Molecules by K. Kuchitsu, E. Hirota, D. A. Ramsay, J. Vogt, N. Vogt (auth.), K. Kuchitsu, M. Tanimoto, N. Vogt (eds.)