By John R. Manning (auth.), A. R. Cooper, A. H. Heuer (eds.)

ISBN-10: 1468431501

ISBN-13: 9781468431506

ISBN-10: 1468431528

ISBN-13: 9781468431520

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Extra info for Mass Transport Phenomena in Ceramics

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30 Figure 5 -- The values of fllK versus the deviation from stoichiometry for iron diffusion in Fel-xD fran Chen and Peterson [19]. Figure 5 [19] shows the values of fllK, which \\7&e measured by the simultaneous diffusion of 52pe and 59pe in Fel-xC, plotted as a function of deviation fran stoichiometry. It is noted from Fig. 5 that the values of fllK are independent of terperature within the limit of experimental error at a given cCmposition, but they decrease with an increase in deviation from stoichianetry.

LE CIAIRE may need to be invoked in discussing atom migration in many types of non-stoichianetric carpoW1ds [10], but little study has so far been made of their modes of migration or of the associated correlation effects. 4. THE CAICULATION OF CORRElATION FACI'ORS Space forbids anything IIDre than a brief :rrention of the three general methods that have been used to calculate correlation factors. These are (a) random walk methods (b) Monte-Carlo methods and (c) nett flux methods. Random Walk Methods [7,8,12-15] These start from equations like (9), (11) or (14) and calculate ' etc.

K. Dawson, Thesis. Univ. of Reading (1968). C. J. Friauf, J. Phy. Chem. Solids 31 825 (1970). S. A. Huggins, J. Chem. Phys. 54 414 (1971) and J. E1ectrochan. Soc. 118 1 (1971). J. W. D. H. Rowe, Houston (Texas) meeting of the E1ectrochem. Soc. H. D. Ie Claire, Unpublished. W. D. Ie Claire, Proc. Brit. ceram. Soc. D. Le Claire, Phil. Mag. 14 1271 (1966). L. W. D. Ie Claire, Jl. of Phys. C. 6 2020 (1973). W. N. H. Rowe, AERE Rept. R 6607 (1970). M. L. Volpe, N. L. Peterson and J. Reddy, Phys. Rev.

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Mass Transport Phenomena in Ceramics by John R. Manning (auth.), A. R. Cooper, A. H. Heuer (eds.)


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