By K.N. Rao (Eds.)
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Additional resources for Molecular Spectroscopy. Modern Research
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Nearly all experiments have employed cylindrical cavities operating in T E modes and Fig. 5 illustrates 0 1 1 34 ALAN CARRINGTON MAGNETIC FIELD - > — E L E C T R I C FIELD FIG. 5. Microwave electric and magnetic fields in the T E n mode. 0 the distribution of microwave magnetic and electric fields in the T E mode. For the observation of electric dipole transitions it is best t o orient the cavity with the cylinder axis parallel to the static magnetic field. Moreover, since the microwave electric field is a maximum approximately midway between the center of the cavity and the cylinder walls, this is where the free-radical concentration should also be maximized.
J. Myers,/. Phys. 42,1837 (1965). A. Carrington, D . H. Levy, and T. A. Miller, Proc. Roy. Soc. Ser. A 2 9 3 , 1 0 8 (1966). A. Carrington, G. N. Currie, D. H. Levy, and T. A. Phys. 17, 535 (1969). A. Carrington, D. H. Levy, and T. A. Miller, Proc. Roy. Soc. Ser. A 2 9 8 , 340 (1967); J. M. Daniels and P. B. Dorain, / . Chem. Phys. 4 5 , 2 6 (1966). T. Amano, E. Hirota, and Y. Phys. Soc. Jap. 2 2 , 399 (1967); F. X. Powell and D. R. Lide, / . Chem. Phys. 4 1 , 1413 (1964); M. Winnewisser, Κ. V.
Molecular Spectroscopy. Modern Research by K.N. Rao (Eds.)