By K.N. Rao (Eds.)

ISBN-10: 012580640X

ISBN-13: 9780125806404

ISBN-10: 0323150373

ISBN-13: 9780323150378

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Mol. Spectrosc. 2 3 , 359 (1967). 130. G. Herzberg, Rev. Mod. Phys. 14,219 (1942). 131. H. H. Nielsen,Phys. Rev. 75,1961 (1949); 7 7 , 130(1950). 132. M. L. Grenier-Besson,ZZ%s. Radium2\, 555 (1960). 133. T. Oka,/. 41, 5410(1967). 134. R. G. Shulman and C. H. Townes, Phys. Rev. 11, 421 (1950). 135. A . G . Maki,/. Mol. Spectrosc. 23,110(1967). 136. W. J. Lafferty, / . Mol. Spectrosc. 25, 359 (1968). 137. A. G. Maki and D. R. ,/. Phys. 41, 3206 (1967). 138. M. Winnewisser and H. K. Bodenseh, Z. Naturforsch.

Nearly all experiments have employed cylindrical cavities operating in T E modes and Fig. 5 illustrates 0 1 1 34 ALAN CARRINGTON MAGNETIC FIELD - > — E L E C T R I C FIELD FIG. 5. Microwave electric and magnetic fields in the T E n mode. 0 the distribution of microwave magnetic and electric fields in the T E mode. For the observation of electric dipole transitions it is best t o orient the cavity with the cylinder axis parallel to the static magnetic field. Moreover, since the microwave electric field is a maximum approximately midway between the center of the cavity and the cylinder walls, this is where the free-radical concentration should also be maximized.

J. Myers,/. Phys. 42,1837 (1965). A. Carrington, D . H. Levy, and T. A. Miller, Proc. Roy. Soc. Ser. A 2 9 3 , 1 0 8 (1966). A. Carrington, G. N. Currie, D. H. Levy, and T. A. Phys. 17, 535 (1969). A. Carrington, D. H. Levy, and T. A. Miller, Proc. Roy. Soc. Ser. A 2 9 8 , 340 (1967); J. M. Daniels and P. B. Dorain, / . Chem. Phys. 4 5 , 2 6 (1966). T. Amano, E. Hirota, and Y. Phys. Soc. Jap. 2 2 , 399 (1967); F. X. Powell and D. R. Lide, / . Chem. Phys. 4 1 , 1413 (1964); M. Winnewisser, Κ. V.

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