By R.E. Banks, B.E. Smart, J.C. Tatlow
During the prior fifteen years advertisement curiosity in compounds containing carbon fluorine bonds has burgeoned past all expectancies, typically because of enterprise possibilities bobbing up from paintings on biologically lively fluoroorganics-particularly agrochemicals, the relentless look for new markets for fluoropolymers and fluoro carbon fluids, advancements within the box of scientific diagnostics, and the force to discover replacements for ozone-depleting CFCs and Halon fire-extinguishing brokers. Judging the location to warrant the booklet of a finished selection of up to date stories facing advertisement organofluorine compounds inside of a unmarried quantity of conceivable dimension (and consequently average cost), we have been extremely joyful to be invited by means of Plenum Publishing company to provide an appropriate booklet. to be able to supply an actual and wide-ranging account of present advertisement functions of fluoroorganic fabrics, it truly used to be essential to gather a large group of a professional contributing authors chosen nearly solely from undefined. via their efforts we've been capable of produce a virtually whole insurance of the modem organofluorochemicals company in a way designed to draw a reader send starting from specialists within the box, via chemists and technologists presently blind to the level of commercial involvement with fluoroorganics, to scholars of utilized chemistry. Promised chapters devoted to perfluoroolefin oxides and 18F labeling of radiopharmaceuticals did not materialize. this can be slightly unlucky in view of our objective to accomplish complete assurance of the subject.
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Extra resources for Organofluorine Chemistry: Principles and Commercial Applications
Watanabe and T. Nakajima, in: Preparation. E. ), p. 297, Wiley (Halstead Press), New York (1982) for more detailed historical information and references. F. Swarts, Bull. Sci. Acad. Roy. Belg. 17,27 (1931). O. Ruff and O. Bretschneider, Z Anorg. AUg. Chem 210, 173 (1933). E. G. Locke, W. R Brode, and A. L. Henne, J. Am Chem Soc. 56, 1726 (1934). J. H. Simons and L. P. Block, J. Am Chem Soc. 59, 1407 (1937). J. H. Simons and L. P. Block, J. Am Chem Soc. 61,2%2 (1939). See also J. H. Simons, in: Fluorine Chemistry (J.
V. Grosse, E. J. Barber, L. L. Burger, and Z. D. Sheldon, Ind. Eng. Chem 39, 290 (1947). R D. Fowler, W. B. Burford, J. M. Hamilton, R G. Sweet, C. E. Weber, J. S. Kasper, and I. Litant, Ind. Eng. Chem 39,292 (1947). R W. Clark, The Greatest Power on Earth, Sidgwick and Jackson, London (1980). T. Abe and S. Nagase, in: Preparation Properties, and Industrial Applications of Organojluorine Compounds (R. E. ), p. 19, Halstead Press (John Wiley), New York (1982). A. A. Banks, H. J. Emeleus, R N. Haszeldine, and V.
CHFCICHCh + Zn -+ CHF=CHCl, and CF~rCH~r + K2C03 -+ CF2=CHBr (alkoxides, such as NaOCH3, were often used as bases, but gave ethers as well as oleftns). Swarts made mono-, di-, and trifluoroethylene by these methods. Fluorinated carboxylic acids RCOili, where R = CHF2, CF~r, CF2Cl, CFBr2, CFCffir, CH~, CHFBr, and CHFI, were synthesized, either by oxidative fluorination of haloacyl halides or by direct chlorinationlbromination of C-H bonds. This work established the principle that clusters containing fluorine are fairly stable and that, in competitive situations, C-F bonds do not usually break as readily as do other halogen-carbon bonds.
Organofluorine Chemistry: Principles and Commercial Applications by R.E. Banks, B.E. Smart, J.C. Tatlow