By Stephen J. Clarson, John J. Fitzgerald, Michael J. Owen, Steven D. Smith, Mark E. Van Dyke
content material: advent --
Surfaces and interfaces --
Silica and comparable systems.
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Additional resources for Science and Technology of Silicones and Silicone-Modified Materials
Polym Chem. , 1989, 27, 3951. ; Zonca, Jr. M RadTech Report, 2004, May/June, 36. V. Polym. Mater. Sci. Eng. , 2003, 89, 279. V. Polym. Prepr. 2004, 45(1), 587-588. ; Jang, M . J. Macromol. : Pure and Appl. Chem. 2005, A42(1), 1-19. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2007. Chapter 4 Fluorinated Copoly(carbosiloxane)s: Synthesis, Copolymerization, and Cross-Linked Networks 1,3 1 2 Melissa A . Grunlan , Nam S. Lee , John A. Finlay , James A. Callow , Maureen E. Callow , and William P.
Preparation of cross-linkedfilms(VIIa-c, VIIIa-c, and IXa-c). Mechanical, Surface, and Thermal Properties of Films The mechanical properties of the films (VIIa-c, VIIIa-c, and IXa-c) were determined by dynamic mechanical thermal analysis (DMTA) (Figure 5). Storage modulus (G') increased over the measured temperature range (-130 to 30 °C) in the order: c < b < a. IXa displayed the highest overall values of G \ For films prepared with the same α,ω-diaminoalkane (a-c), G ' typically increased with higher levels of fluorination in the order: VII < VIII < IX.
2 Cross-linking of Non-fluorinated and Fluorinated a,œ-Bis(glycidyloxypropyl)pentasiloxanes with α,ω-Diaminoalkanes Fluorinated copoly(carbosiloxane)s bearing pendant epoxy end-groups may be cross-linked to form solid networks or films with interesting properties. Epoxy resins are extensively used in adhesives, coatings, composites, and electronics packaging. They demonstrate high resistance to chemicals, solvents, corrosion, and electricity as well as high modulus, tensile strength, and dimensional stability (22,23).
Science and Technology of Silicones and Silicone-Modified Materials by Stephen J. Clarson, John J. Fitzgerald, Michael J. Owen, Steven D. Smith, Mark E. Van Dyke