By Liz Climo

ISBN-10: 0762455462

ISBN-13: 9780762455461

Artist Liz Climo has charmed her lovers along with her comedian international of whimsical animal characters, the place every person from grizzly bears, dinosaurs, rabbits, and anteaters grapple with lifestyle with wit and humor. via her comics, we find that an armadillo can costume for Halloween, a dinosaur could be a loving mum or dad ... and a rhino can squeeze orange juice! This new assortment good points greater than a hundred of her comics, starring her loved characters in all types of humorous occasions, from celebrating vacation trips to assisting pals.

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Extra info for The Little World of Liz Climo

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C h e m i c a l Properties In the following Sections the chemical properties of biguanide and its derivatives are systematically considered. Attention may be drawn to the particularly extensive and detailed recent studies concerning biguanides 412 The Chemistry of Biguanides as sources of guanamines and pyrimidines (Section H). The basic nature and properties of biguanides have already been dealt with in Section VI B. A. Thermal Decomposition 1. Arylbiguanides The thermal decomposition of phenylbiguanide, both in the presence and absence of ammonium chloride and aniline hydrochloride, has been studied in some detail (669) with the following results (equations 1 and 2, R ----Ph) : R _ N H .

The reaction has been extended to 1,1disubstituted biguanides (548) and to several other examples (767, 527). 419 F. Kurzer and E. D. Pitchfork H . Condensation w i t h Esters The reaction of biguanides with esters was first studied in detail by Rackmann (578) who showed that ethyl formate and arylbiguanides gave 2,4-diamino-6-substituted s-triazines (LXXXIII, where R', R" and R" may vary widely). ~NIII q- AlkOH +HgO NHR' (LXXXm} 1. Saturated Esters In 1940, phenylbiguanide and ethyl formate were reported (735) to react at room temperature to give a triazine, also formed on fusion of phenylbiguanide and diphenylformamide at 145 ~ Further experience gained with Paludfine (t55)showed that the products were N~-arylguanamines (LXXXII[; R ' = P h , R ' : R m = H ; or R'=p-C1C~H4; R*=Pr~; R " ~ H).

In the presence of too high a concentration of acid, however, amidinoureas will result (572, 730). Thus, the appropriate reactants give the desired 1-arylbiguanides in boiling 12% hydrochloric acid, but yield N-amidino-N'arylureas in 22% acid. Since 22% hydrochloric acid converts the biguanide into the amidinourea (730), support is provided for the primary formation of the biguanides. NH2 II n 0 NFI A r N H 2 + HsN" C. N H . CN 22% HCI Zl NH ""~0/-"* A r N H 9C- N H . C. N H s II Ii NH NH Time, as well as acid concentration, is a factor controlling the nature of the product.

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The Little World of Liz Climo by Liz Climo


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