By Christoph A. Schalley, Fritz Vögtle

ISBN-10: 3540006699

ISBN-13: 9783540006695

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38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. 60. 61. 62. 63. 64. 65. 66. 67. 68. 69. 70. 71. 72. 73. 74. 75. 76. 77. 35 Paulo C, Puskas JE (2001) Macromolecules 34:734 Hong C-Y, Pan C-Y (2002) Polymer Int 51:785 Mori H, Chan Seng D, Lechner H, Zhang M, Müller AHE (2002) Macromolecules 35:9270 Kennedy JP, Frisch KC Jr (1982) US4327201; US4442261 Nuyken O, Gruber F, Pask SD, Riederer A, Walter M (1993) Makromolekulare Chemie 194:3415 Jones GD, Runyon JR, Ong J (1961) J Appl Polymer Sci 5:452 Powers KW, Kuntz I (1978) US4074035 Hazer B (1992) Makromol Chem 193:1081 Hazer B (1991) Macromol Rep A28 (Supp 1):47 Müller AHE, Yan D, Wulkow M (1997) Macromolecules 30:7015 Puskas JE, Grasmueller M (1998) Macromol Symp 132:117 Radke W, Litvinenko GI, Müller AHE (1998) Macromolecules 31:239 Yoo SH, Yoon TH, Jho JY (2001) Macromol Rapid Commun 22:1319 Yoo SH, Lee JH, Lee J-C, Jho JY (2002) Macromolecules 35:1146 Bibiao J, Yang Y, Xiang J, Rongqi Z, Jianjun H, Wenyun W (2001) Eur Poly J 37:1975 Bibiao J, Yang Y, Jian D, Shiyang F, Rongqi Z, Jianjun H, Wenyun W (2002) J Appl Poly Sci 83:2114 Hong CY, Pan CY (2001) Polymer 42:9385 Cheng G, Simon PFW, Hartenstein M, Müller AHE (2000) Macromol Rapid Commun 21:846 Matyjaszewski K, Pyun J, Gaynor SG (1998) Macromol Rapid Commun 19:665 Mori H, Böker A, Krausch G, Müller AHE (2001) Macromolecules 34:6871 Hong Cy, Pan Cy, Huang Y, Xu Zd (2001) Polymer 42:6733 Sakamoto K, Aimiya T, Kira M (1997) Chem Lett 1245 Ishizu K, Shibuya T, Mori A (2002) Polym Int 51:424 Ishizu K, Mori A, Shibuya T (2002) Des Monomers Polym 5:1 Ishizu K, Mori A (2000) Macromol Rapid Commun 21:665 Ishizu K, Mori A (2001) Polym Int 51:50 Ishizu K, Ohta Y, Kawauchi S (2002) Macromolecules 35:3781 Lu P, Paulasaari J, Weber WP (1996) Macromolecules 29:8583 Zhang H, Ruckenstein E (1997) Polym Bull (Berlin) 39:399 Aoshima S, Fréchet JMJ, Grubbs RB, Henmi M, Leduc L (1995) Polym Prepr (Am Chem Soc Div Polym Chem) 36:531 Sunder A, Hanselmann R, Frey H, Mülhaupt R (1999) Macromolecules 32:4240 Hobson LJ, Feast WJ (2000) J Mater Chem 10:609 Zhang X, Liu WH, Chen YM, Gong AJ, Chen CF, Xi F (1999) Polym Bull (Berlin) 43:29 Guan Z (2002) J Am Chem Soc 124:5616 Kadokawa J, Ikuma K, Tagaya H (2002) J Macromol Sci Pure Appl Chem A39:879 Matyjaszewski K, Editor (2000) Controlled/living radical polymerization.

In this chapter, we summarize recent developments in the synthesis of organometallic dendrimers, in which organometallic species act as building block in every generation. Such dendrimers are generated by successive reactions characteristic of organometallic complexes, and some of them show interesting properties. Keywords. Metallodendrimer, Organometallic complex, Metal acetylide 1 Introduction . . . . . . . . . . . . . . . . 40 2 Dendrimers Based on Alkyl-Metal Complexes . . .

5] independently initiated such studies by using polypyridine Ru complexes in the early 1990s. Organometallic dendrimers offer several advantages for tailoring dendritic molecules with desirable functionalities due to not only the availability of a wide variety of organic compounds that coordinate to many kinds of metal atoms but also the flexibility of the coordination modes between metal atoms and organic ligands. The appropriate choice of organometallic complexes for the core and the building block allows us to design a novel dendritic molecule in which the number and position of the metallic species are precisely controlled, and specific applications such as catalysts, multi-redox system, and molecular sensors are realized [6].

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Topics in current chemistry, 228, Dendrimers V: Functional and Hyperbranched Building Blocks, Photophysical Properties, Applications in Materials and Life Sciences by Christoph A. Schalley, Fritz Vögtle


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